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Wondering if a day trip to Venice from Vicenza might be enough, although I heard Venice is so nice at night after the cruise crowds etc. leave...If I stayed in Vicenza for four nights instead of in Venice, I could probably day trip to Verona and/or Padua as well before heading to Florence.
Would you really love to stay in Vicenza or just to use it as a base. If just for a base to see Padua and Verona in addition to Venice, then stay in Venice. You can do day trips to Padua and Verona easily from Venice. You will have more to do in Venice.