Looking to finalize an overnight trip to Toledo from Madrid on June 3. Need to get back to the Atocha station for a 9.00 am connecting rail trip to Valencia . Ealiest train I can find reaches Madrid around 9.00 am. Seems a bit late for workers wishing to travel to Madrid. Perhaps the early ones are booked out. We will have two pieces of luggage. Do the buses cater for this and how early do they travel. Can tickets on buses be pre booked?